ISOSTRUCTURAL ETA-2-DIHYDROGEN COMPLEXES [OS(NH3)5(H2)]2+,[OS(NH3)5(H2)]3+ AND THE HYDROGENATION OF ACETONE

被引：89

作者：

HARMAN, WD ^{[1
]}

TAUBE, H ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 06期

关键词：

D O I：

10.1021/ja00162a028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of Os(NH3)5(CF3SO3)3 in methanol or aqueous solution affords the dihydrogen complex [Os-(NH3)5(H2)]2+, [1]2+. The one-electron oxidation of this species generates a trivalent dihydrogen complex [1]3+ which, unlike its precursor, is capable of hydrogenating acetone to isopropyl alcohol. The use of methanol as a solvent offers important advantages for the preparation of a number of Os(II) complexes over other nonaqueous solvents previously used. © 1990, American Chemical Society. All rights reserved.

引用

页码：2261 / 2263

页数：3

共 50 条

[1] ELECTROCHEMISTRY OF OS(III) AMMINES .1. OS(NH3)5(H2O)3+, OS(NH3)5(OH)2+
GULENS, J
PAGE, JA
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 55 (02): : 239 - 253
[2] REDUCTION OF [OS(NH3)5(ETA-1-CH3CN)]2+ TO [OS(NH3)5(ETA-2-CH3CH=NH2)]3+
HASEGAWA, T
KWAN, KS
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[J]. INORGANIC CHEMISTRY, 1992, 31 (09) : 1598 - 1600
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PREETZ, W
BUTJE, K
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 557 (02): : 112 - 122
[4] ELECTROCHEMISTRY OF OS(III) AMMINES .2. OS(NH3)5CL2+, OS(NH3)5I2+, OS(NH3)3+6
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PAGE, JA
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1976, 67 (02): : 215 - 230
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