OXIDATION OF CATECHOL AND OF 2,6-DI-TERT-BUTYLPHENOL BY DIOXIRANES

被引：25

作者：

ALTAMURA, A ^{[1
]}

FUSCO, C ^{[1
]}

D'ACCOLTI, L ^{[1
]}

MELLO, R ^{[1
]}

PRENCIPE, T ^{[1
]}

CURCI, R ^{[1
]}

机构：

[1] UNIV BARI, CTR CNR MISO, DIPARTIMENTO CHIM, VIA AMENDOLA 173, I-70126 BARI, ITALY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

D O I：

10.1016/0040-4039(91)80054-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In a biomimetic transformation, the selective oxidation of catechol (2) to Z,Z-muconic acid (3) has been achieved under extremely mild conditions using methyl(trifluoromethyl)dioxirane (1b). Both dioxirane 1b and dimethyldioxirane (1a) have been applied to the oxidation of 2,6-di-tert-butylphenol (4); the product natures suggest the incursion of radical pathways.

引用

页码：5445 / 5448

页数：4

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