CYCLODEXTRIN STATIONARY PHASES FOR THE GAS SOLID CHROMATOGRAPHIC-SEPARATION OF INORGANIC GASES

被引：9
|
作者：
REID, GL [1 ]
WALL, WT [1 ]
ARMSTRONG, DW [1 ]
机构：
[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401
来源：
JOURNAL OF CHROMATOGRAPHY | 1993年 / 633卷 / 1-2期
关键词：
D O I：
10.1016/0021-9673(93)83148-L
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Cyclodextrins linked to silica gel are used as gas-solid chromatographic stationary phases. They provide an effective means for separating a wide variety of gases. Evaluation of different cyclodextrin columns and the analogous silica gel support column with inorganic gas standards is reported. Separation selectivities and efficiencies differ between silica gel and the cyclodextrin phases. Capacity factors and chromatograms are presented for these gas-solid chromatographic stationary phases. The native cyclodextrin stationary phases appear to retain gases via at least two different retention mechanisms.
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收藏
页码：143 / 149
页数：7
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