Cysteine as a non-toxic corrosion inhibitor for copper alloys in conservation

被引:10
|
作者
Gravgaard, Mari [1 ]
van Lanschot, Jettie [1 ]
机构
[1] Konservatorskolen, Esplanaden 34, DK-1263 Copenhagen K, Denmark
关键词
bronze disease; inhibitor; cysteine; benzotriazole (BTA); electrochemical measurements; corrosion;
D O I
10.1080/19455224.2012.681618
中图分类号
C [社会科学总论];
学科分类号
03 ; 0303 ;
摘要
The aim of this work is to examine cysteine as an alternative to benzotriazole (BTA) for the conservation of archaeological objects with bronze disease. Investigation of the two inhibitors involved the use of electrochemical techniques, measurements of weight change in high humidity and comparative studies of colour changes in the corrosion products. The results obtained in this article demonstrate that cysteine could be a non-toxic alternative to BTA. Cysteine performed as well as BTA on pre-corroded coupons with bronze disease in high humidity and showed acceptable results during testing for colour alteration on real archaeological objects.
引用
收藏
页码:14 / 24
页数:11
相关论文
共 50 条
  • [1] Caffeine as non-toxic corrosion inhibitor for copper in aqueous solutions of potassium nitrate
    Fallavena, Thuanny
    Antonow, Muriel
    Goncalves, Reinaldo Simoes
    APPLIED SURFACE SCIENCE, 2006, 253 (02) : 566 - 571
  • [2] Natural alkaloid as a non-toxic, environmentally friendly corrosion inhibitor
    Ng, Jun H.
    Almubarak, Tariq
    Nasr-El-Din, Hisham
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2022, 100 (06): : 1214 - 1225
  • [3] Evaluation of non-toxic corrosion inhibitors for copper in sulphuric acid
    Stupnisek-Lisac, E
    Gazivoda, A
    Madzarac, M
    ELECTROCHIMICA ACTA, 2002, 47 (26) : 4189 - 4194
  • [4] Evaluation of new non-toxic corrosion inhibitors for conservation of iron artefacts
    Hollner, S.
    Mirambet, F.
    Rocca, E.
    Reguer, S.
    CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, 2010, 45 (05) : 362 - 366
  • [5] Surface modification of aluminum alloys: Non-toxic processes for improved corrosion resistance
    Mansfeld, F
    PROCEEDINGS OF CORROSION 98 - RESEARCH TOPICAL SYMPOSIUM ON CORROSION IN ADVANCED MATERIALS AND SYSTEMS, 1998, : 81 - 103
  • [6] An Expired Non-Toxic Diltiazem Hydrochloride as Corrosion Inhibitor for Cu in Nitric Acid Medium
    Fouda, A. S.
    Rashwan, S. M.
    Kamel, M.
    Badawy, A. A.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (03): : 1952 - 1969
  • [7] Repurposing Griseofulvin as a Non-Toxic Angiogenesis Inhibitor
    Pasha, Sheik Pran Babu Sardar
    White, Darcy
    Corson, Timothy W.
    FASEB JOURNAL, 2018, 32 (01):
  • [8] Study of the anticorrosive behaviour of epoxy binders containing non-toxic inorganic corrosion inhibitor pigments
    de Lima-Neto, Pedro
    de Araujo, Alexsander P.
    Araujo, Walney S.
    Correia, Adriana N.
    PROGRESS IN ORGANIC COATINGS, 2008, 62 (03) : 344 - 350
  • [9] Inhibition of copper aqueous corrosion by non-toxic linear sodium heptanoate: mechanism and ECAFM study
    Rocca, E
    Bertrand, G
    Rapin, C
    Labrune, JC
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 503 (1-2) : 133 - 140
  • [10] Potent inhibition of copper corrosion in neutral chloride media by novel non-toxic thiadiazole derivatives
    Tian, H.
    Li, W.
    Cao, K.
    Hou, B.
    CORROSION SCIENCE, 2013, 73 : 281 - 291