Comparison between hydrogen-transfer and fluoro-transfer reactions on the microcanonical unimolecular rate constants

被引：0

作者：

Feng, WL ^{[1
]}

Zhang, SW ^{[1
]}

Wang, Y ^{[1
]}

Wu, JN ^{[1
]}

Li, ZH ^{[1
]}

机构：

[1] BEIJING NORMAL UNIV,DEPT CHEM,BEIJING 100875,PEOPLES R CHINA

来源：

CHINESE JOURNAL OF CHEMISTRY | 1995年 / 13卷 / 05期

关键词：

microcanonical rate constant; tunneling effect; curvature correction;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The microcanonical rate constants for the hydrogen-transfer process of HCCF (reaction 7) and the fluoro-transfer process of FCCF (reaction 8) are carried out with tunneling correction and curvature correction. The results show that the tunneling effects and curvature effects on the rate constant of reaction 7 is quite different from that of reaction 8. The rate constants for different rotational states are also studied for these reactions.

引用

页码：391 / 395

页数：5

共 50 条

[1] Comparison between hydrogen-transfer and fluoro-transfer reactions on the microcanonical unimolecular rate constants
FENG
[J]. Chinese Journal of Chemistry, 1995, (05) : 391 - 395
[2] CALCULATION OF THE MICROCANONICAL RATE CONSTANTS FOR THE HYDROGEN-TRANSFER REACTION OF FLUORO-SUBSTITUTED ACETYLENE
LI, ZH
WANG, Y
ZHANG, SW
FENG, WL
LIU, RZ
[J]. ACTA CHIMICA SINICA, 1995, 53 (04) : 323 - 327
[3] CONTROLLING RADICAL-CHAIN REACTIONS BY UNIMOLECULAR CHAIN TRANSFER - INTRAMOLECULAR HYDROGEN-TRANSFER REACTIONS OF SILICON HYDRIDES
CURRAN, DP
XU, JY
LAZZARINI, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (24) : 6603 - 6604
[4] Microcanonical Rate Constants for Unimolecular Reactions in the Low-Pressure Limit
Jasper, Ahren W.
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 124 (07): : 1205 - 1226
[5] HYDROGEN-TRANSFER REACTIONS CATALYZED BY FULLERENES
MALHOTRA, R
MCMILLEN, DF
TSE, DS
LORENTS, DC
RUOFF, RS
KEEGAN, DM
[J]. ENERGY & FUELS, 1993, 7 (05) : 685 - 686
[6] Calculation on the Microcanonical Unimolecular Rate Constants for the Vibrational-state-selected Reactions
Feng Wenlin
Wang Yan
Zhang Shaowen
Li Zonghe
[J]. ACTA PHYSICO-CHIMICA SINICA, 1995, 11 (08) : 716 - 718
[7] THE MARCUS CROSS RELATION FOR HYDROGEN-TRANSFER REACTIONS
SUHNEL, J
[J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (05) : 281 - 286
[8] COPPER-CATALYSED HYDROGEN-TRANSFER REACTIONS
BACON, RGR
RENNISON, SC
STEWART, OJ
[J]. PROCEEDINGS OF THE CHEMICAL SOCIETY OF LONDON, 1964, (DEC): : 409 - &
[9] REACTIONS INVOLVING HYDROGEN TRANSFER .3. HYDROGEN-TRANSFER BETWEEN OMICRON,OMICRON'-BRIDGED TETRAARYLETHYLENES AND DIARYLMETHANES
SCHONBERG, A
SINGER, E
ESCHENHOF, B
[J]. CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (05): : 1763 - 1768
[10] Uncatalyzed transfer hydrogenation and transfer hydrogenolysis: Two novel types of hydrogen-transfer reactions
Ruchardt, C
Gerst, M
Ebenhoch, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (13-14) : 1407 - 1430

← 1 2 3 4 5 →