4-{[4-(Dimethylamino)benzylidene]-aminolbenzenesulfonamide

被引:5
|
作者
Durgun, Mustafa [1 ]
Turkmen, Hasan [1 ]
Tunc, Tuncay [2 ]
Hokelek, Tuncer [3 ]
机构
[1] Harran Univ, Dept Chem, TR-63300 Sanliurfa, Turkey
[2] Aksaray Univ, Sci Educ Dept, TR-68100 Aksaray, Turkey
[3] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey
关键词
D O I
10.1107/S1600536814012136
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title Schiff base compound, C15H17N3O2S, is non -planar with a dihedral angle of 69.88 (4)degrees between the planes of the benzene rings. In the crystal, pairs of N-H center dot center dot center dot N hydrogen bonds, between the sulfonamide nitrogen-H atom and the azomethine N atom, link the molecules into inversion dimers, forming R-2(2)(16)degrees ring motifs. These dimers are linked by NH center dot center dot center dot O hydrogen bonds, between the sulfonamide nitrogen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped pi-pi interactions involving inversion-related benzene sulfonamide rings [centroid-centroid distance = 3.8800 (9) angstrom; normal distance = 3.4796 (6) angstrom; slippage = 1.717 angstrom].
引用
收藏
页码:O726 / +
页数:9
相关论文
共 50 条
  • [1] N′-[4-(Dimethylamino)benzylidene]benzohydrazide
    Cui, Chuansheng
    Meng, Qingan
    Wang, Yong
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2472 - +
  • [2] N′-[4-(Dimethylamino)benzylidene]acetohydrazide
    Li, Wei-Wei
    Yu, Tie-Ming
    Yu, Wen-Bo
    Lv, Lu-Ping
    Hu, Xian-Chao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2197 - U2394
  • [3] N′-[4-(Dimethylamino)benzylidene]4-methoxybenzohydrazide
    Lu, Jiu-Fu
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2033 - U4766
  • [4] 1-[4-(Dimethylamino)benzylidene]-4-(4-nitro-phenyl)thiosemicarbazide
    Fang, Wei
    Lin, Li-Rong
    Huang, Rong-Bin
    Zheng, Lan-Sun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O112 - O113
  • [5] N-[4-(Dimethylamino)benzylidene]-4-methylaniline
    Balachandar, R. K.
    Kalainathan, S.
    Eappen, Shibu M.
    Podder, Jiban
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O905 - +
  • [6] N-[4-(Dimethylamino)benzylidene]-4ethoxyaniline
    Wang, Qiang
    Wang, Da-Qi
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O51 - U2952
  • [7] 1-[4-(Dimethylamino)benzylidene]-4-methylthiosemicarbazide
    Li, Yu-Feng
    Jian, Fang-Fang
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1397 - U1343
  • [8] Synthesis, Spectral Characterization, Thermal and Optical Studies of Novel Complexes: 4-(Dimethylamino)benzylidene-4-acetamideaniline and 4-(Dimethylamino)benzylidene-4-nitroaniline
    Umesh Neupane
    R. N. Rai
    [J]. Journal of Fluorescence, 2017, 27 : 2263 - 2277
  • [9] Synthesis, Spectral Characterization, Thermal and Optical Studies of Novel Complexes: 4-(Dimethylamino)benzylidene-4-acetamideaniline and 4-(Dimethylamino)benzylidene-4-nitroaniline
    Neupane, Umesh
    Rai, R. N.
    [J]. JOURNAL OF FLUORESCENCE, 2017, 27 (06) : 2263 - 2277
  • [10] 4-[4-(Dimethylamino)benzylidene]-2,6-dimethylcyclohexa-2,5-dienone
    Hampel, Nathalie
    Richter, Dorothea
    Ofial, Armin R.
    Mayr, Herbert
    Mayer, Peter
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2102 - U1561