REGIOSELECTIVITY STUDIES BY SELECTIVE DETECTION OF LONG-RANGE HETERONUCLEAR COUPLINGS FROM THE SDEPT-1D METHOD

被引：17
|
作者：
PARELLA, T [1 ]
SANCHEZFERRANDO, F [1 ]
VIRGILI, A [1 ]
机构：
[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1994年 / 32卷 / 06期
关键词：
SELECTIVE DEPT; LONG-RANGE; H-1-C-13; COUPLINGS; DELECTIVE ALLYLATION;
D O I：
10.1002/mrc.1260320606
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Some regiosomers formed by palladium(0)-catalysed allylation of several ambident heterocyclic nucleophiles, among others, were easily distinguished in very short spectrometer times by selective polarization transfer via DEFT from well resolved protons to long-range coupled carbons using the SDEPT-1D experiment. This pulse sequence was also analysed in terms of the product operator formalism. These structural elucidations can provide useful information about the regioselectivity in these reactions.
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收藏
页码：343 / 347
页数：5
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