Bisdiselenolate metal complexes. Synthesis, structure and electrochemical properties

被引：3
|
作者：
Liu, SG
Liu, YQ
Yang, XY
Zhu, DB
机构：
[1] Institute of Chemistry, Academia Sinica, Beijing 100080, Peoples
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1995年 / 105卷 / 1-4期
关键词：
multi-selenium donor ligand; transition metal complex; crystal structure; electrochemical properties; synthetic metals;
D O I：
10.1080/10426509508042050
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multi-selenium donor ligand 2,2-dicyanoethylene-1,1-diselenolate (DCNSe) has been prepared. The dianionic complex of DCNSe with Ni(II) has been isolated as the tetrabutylammonium (TEA) salt. The compound is characterized by negative ion Fast Atom Bombardment (FAB) mass spectral analysis, Fourier Transform Infrared (FT-IR) spectral analysis, UV-Vis spectral analysis and cyclic voltammetry. The electrochemical properties and crystal structure are studied as well. In addition, the corresponding Cu(II) complex has been isolated as the TEA salt and characterized by negative ion FAB mass spectral analysis and FT-IR spectral analysis.
引用
收藏
页码：83 / 91
页数：9
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