REACTION OF PHENYLCHLOROCARBENE WITH [1.1.1]PROPELLANE - ABSOLUTE RATE CONSTANTS AND MECHANISM

被引：7
|
作者：
SCAIANO, JC
MCGARRY, PF
机构：
[1] Department of Chemistry, University of Ottawa, Ottawa
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 08期
关键词：
D O I：
10.1016/S0040-4039(00)91764-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Phenylchlorocarbene adds to [1.1.1] propellane with rate constants of 6.1 x 10(7) and 8.8 x 10(6) M-1s-1 in cyclohexane and acetonitrile respectively to produce adduct V in good yields. No evidence for a biradical intermediate was obtained.
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页码：1243 / 1246
页数：4
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