HELIUM ATOM AS A PROBE OF MOLECULAR SHAPE AND PROPERTIES - HE-H2O COMPLEX

被引：18
|
作者：
KUKAWSKATARNAWSKA, B
CHALASINSKI, G
SZCZESNIAK, MM
机构：
[1] UNIV WARSAW,DEPT CHEM,UL PASTEURA 1,PL-02093 WARSAW,POLAND
[2] SO ILLINOIS UNIV,DEPT CHEM & BIOCHEM,CARBONDALE,IL 62901
[3] OAKLAND UNIV,DEPT CHEM,ROCHESTER,MI 48309
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 297卷
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/0022-2860(93)80186-Y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It has been demonstrated on the He-H2O example that the He atom may serve as a reliable probe to analyse the anisotropy of ''molecular ability'' to participate in exchange, induction, SCF-deformation and dispersion interactions. We have also proposed a pictorial representation of the anisotropy of molecular ''shape'', related to the exchange repulsion, and molecular ''propensities'', related to induction, SCF-deformation and dispersion interactions.
引用
收藏
页码：313 / 325
页数：13
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