KINETIC-ENERGY RELEASE IN UNIMOLECULAR ION DECOMPOSITION OF SUBSTITUTED BENZOPHENONES

被引：0
|
作者：
ELKADER, FHA
机构：
来源：
INDIAN JOURNAL OF PURE & APPLIED PHYSICS | 1992年 / 30卷 / 08期
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D O I：
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中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
A correlation between log Z*/Z*0 and sigma+ has been observed for the loss of substituted and CO radical from the molecular ions and fragment benzoyl ions, respectively, in para-substituted benzophenones. The kinetic energy release for the reactions studied revealed no correlation with substituent constants of Hammett equations. The enthalpy of the C6H5+ ion formed from C6H5CO+ ion as subsequent reaction has been determined.
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页码：376 / 379
页数：4
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