THE COPOLYMERIZATION OF 2-VINYL AND 3-VINYL THIOPHENE WITH ALPHA-METHYLENE-GAMMA-BUTYROLACTONE

被引:26
|
作者
TRUMBO, DL
机构
[1] The Glidden Company, Strongsville, 44136, OH
关键词
D O I
10.1007/BF00587969
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Binary copolymers of 2- and 3-vinyl thiophene were synthesized via free-radical initiated bulk polymerization. The copolymerizations proceeded readily at 65-degrees-C to yield copolymers of reasonable molecular weight. The 2-vinyl thiophene monomer was found to be more reactive than the a -methylene-gamma-butyrolactone, while the 3-vinyl thiophene was found to be less reactive than the lactone.
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页码:271 / 275
页数:5
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