MOLECULAR-WEIGHT CHARACTERIZATION OF FLUOROPOLYOXYALKYLENES BY GEL-PERMEATION CHROMATOGRAPHY

被引:19
|
作者
GIANOTTI, G
LEVI, M
TURRI, S
机构
[1] POLITECN MILAN,DIPARTIMENTO CHIM IND & INGN CHIM G NATTA,PZA LEONARDO DA VINCI 32,I-20133 MILAN,ITALY
[2] AUSIMONT SPA,CTR RIC SVILUPPO,I-20021 BOLLATE,ITALY
关键词
D O I
10.1002/app.1994.070510601
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conditions required for the molecular weight and molecular weight distribution determination of fluoropolyoxyalkylenes by gel permeation chromatography are reported and discussed. Experimental work was carried out with three series of narrow fractions of oligomers having the same perfluorinated copolymeric body and three different types of chain ends. The same calibration curve describes very well the behavior of the three series of samples, so that a ''size-exclusion'' mechanism of the molecular separation can be postulated practically. (C) 1994 John Wiley & Sons, Inc.
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页码:973 / 978
页数:6
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