SELECTIVE MONO(ALKOXYCARBONYLATION) AND BIS(ALKOXYCARBONYLATION) OF OLEFINS CATALYZED BY PALLADIUM IN THE PRESENCE OF CU(I) OR CU(II) CHLORIDE UNDER REMARKABLY MILD CONDITIONS - APPLICATION TO THE SYNTHESIS OF GAMMA-BUTYROLACTONE DERIVATIVES

被引：42

作者：

TODA, S ^{[1
]}

MIYAMOTO, M ^{[1
]}

KINOSHITA, H ^{[1
]}

INOMATA, K ^{[1
]}

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, MARUNOUCHI 1-1, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 12期

关键词：

D O I：

10.1246/bcsj.64.3600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalyzed mono- and bis(alkoxycarbonylation)s of olefins were controlled by the use of copper(II) and copper(I) chloride, respectively, in alcohol under normal pressure of carbon monoxide and oxygen at room temperature without any other additives. 3-Buten-1-ols gave the corresponding gamma-butyrolactones and 2-oxotetrahydrofuran-3-acetic acid esters, respectively, in high yields.

引用

页码：3600 / 3606

页数：7

共 3 条

[1] SELECTIVE MONOCARBONYLATION AND DICARBONYLATION OF TERMINAL OLEFINS CATALYZED BY PD-C IN THE PRESENCE OF CU(II) OR CU(I) CHLORIDE UNDER MILD CONDITIONS
INOMATA, K
TODA, S
KINOSHITA, H
CHEMISTRY LETTERS, 1990, (09) : 1567 - 1570
[2] Asymmetric bis(alkoxycarbonylation) reaction of homoallylic alcohols catalyzed by palladium in the presence of Cu(I) triflate using the chiral bioxazoline ligand
Ukaji, Y
Miyamoto, M
Mikuni, M
Takeuchi, S
Inomata, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (03) : 735 - 742
[3] Ultrasound promoted facile one pot synthesis of triazole derivatives catalyzed by functionalized graphene oxide Cu(I) complex under mild conditions
Naeimi, Hossein
Shaabani, Rahele
ULTRASONICS SONOCHEMISTRY, 2017, 34 : 246 - 254

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