Ni(II)-8-aminoquinolinato complexes have been prepared. The structures of the complexes were investigated by different analytical and spectral methods. The thermochromic behaviour of the complexes in the solid state is discussed in terms of structural phase change and ligand field strength. The observed phase change was investigated by means of X-ray powder diffraction and the temperature dependence of the electrical conductivity.
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Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, CanadaUniv British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada
Brown, Christopher M.
Carta, Veronica
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Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, CanadaUniv British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada
Carta, Veronica
Wolf, Michael O.
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Univ British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, CanadaUniv British Columbia, Dept Chem, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada