REACTIONS OF MIXTURES OF LIGHT ALKENES AND N-HEPTANE OVER USHY ZEOLITE

被引：1
|
作者：
PINHEIRO, CI
LEMOS, F
RIBEIRO, FR
GUISNET, M
机构：
[1] INST SUPER TECN,DEPT ENGN QUIM,AVE ROVISCO PAIS,P-1096 LISBON,PORTUGAL
[2] UNIV POITIERS,CNRS,UA 350,F-86022 POITIERS,FRANCE
来源：
APPLIED CATALYSIS A-GENERAL | 1994年 / 108卷 / 02期
关键词：
ALKENES; COKING; CRACKING; ETHENE; HEPTANE (N-); PROPENE; ZEOLITES;
D O I：
10.1016/0926-860X(94)85064-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of ethene and propene on the catalytic cracking of n-heptane at 673 K over the USHY zeolite has been studied with mixtures of n-heptane with different concentrations of alkene. The study reveals that the presence of light alkenes, with an alkene-to-n-heptane molar ratio in the range of 0.1-1.2, results in a decrease of the initial cracking activity of n-heptane, and an increase in the yield of heptenes and amount of coke formed. So, for this range of relatively high concentrations of light alkenes studied, die cracking reaction of n-heptane is substantially inhibited by these species.
引用
收藏
页码：107 / 114
页数：8
相关论文
共 50 条
  • [1] HYDROCONVERSION OF N-HEPTANE OVER DEALUMINATED ZEOLITE OMEGA-CATALYSTS
    COQ, B
    RAJAOFANOVA, V
    CHAUVIN, B
    FIGUERAS, F
    APPLIED CATALYSIS, 1991, 69 (02): : 341 - 349
  • [2] Aromatization of n-Heptane over Modified Metal-MFI Zeolite Catalysts
    Asaftei, Iuliean V.
    Bilba, Nicolae
    Sandu, Ion
    REVISTA DE CHIMIE, 2013, 64 (08): : 838 - 843
  • [3] Isomerization of n-heptane over Pt-loaded zeolite beta catalysts
    Wang, ZB
    Kamo, A
    Yoneda, T
    Komatsu, T
    Yashima, T
    APPLIED CATALYSIS A-GENERAL, 1997, 159 (1-2) : 119 - 132
  • [4] Unified kinetics of n-heptane hydroisomerisation over various Pt/zeolite catalysts
    Usman, Muhammad R.
    Alotaibi, Faisal M.
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2016, 41 (02) : 177 - 192
  • [5] Initiation of chain reaction in catalytic pyrolysis of n-heptane over zeolite catalysts
    Wei, X. (weixl.ripp@sinopec.com), 1600, Science Press (29):
  • [6] Oxidation reactions of n-heptane and isooctane
    Simon, Y
    Scacchi, G
    Baronnet, F
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1996, 74 (07): : 1391 - 1402
  • [7] Temperature dependence of the USHY+HZSM-5 mixing effect on the n-heptane transformation
    Dzikh, IP
    Lopes, JM
    Lemos, F
    Ribeiro, ER
    CATALYSIS TODAY, 2001, 65 (2-4) : 143 - 148
  • [8] Kinetic modelling of the catalytic cracking of n-hexane and n-heptane over a zeolite catalyst
    Pinto, RR
    Borges, P
    Lemos, MANDA
    Lemos, F
    Ribeiro, FR
    APPLIED CATALYSIS A-GENERAL, 2004, 272 (1-2) : 23 - 28
  • [9] Combustion properties of n-heptane/hydrogen mixtures
    Comandini, A.
    Chaumeix, N.
    Maclean, J. D.
    Ciccarelli, G.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (03) : 2039 - 2052
  • [10] Influence of the zeolite structure and acidity on the hydroisomerization of n-heptane
    Patrigeon, A
    Benazzi, E
    Travers, C
    Bernhard, JY
    CATALYSIS TODAY, 2001, 65 (2-4) : 149 - 155
12345